Start iChat (or Adium) without logging into services
Before clicking on iChat or Adium, hold down the shift key and continue holding it until the application launches. When the app opens, none of your accounts will be logged in. You can then manually login to individual accounts as necessary. Try it and see!
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Have you ever wanted to open iChat or Adium to check a chat log, account setting, or other information, but didn't want to connect to your...